IGNOU MCH 16 SOLVED ASSIGNMENT

Ques 1.

Give the classification of substitution mechanisms for octahedral complexes.

Ques 2.

Explain the mechanism of substitution reactions in trigonal bipyramidal complexes.

Ques 3.

With a suitable example suggest the order of the reactions of base-catalyzed hydrolyses and predict the mechanism that is followed in them.

Ques 4.

Explain with suitable figures the Bailar twist mechanism followed in intramolecular racemization reactions.

Ques 5.

Explain the dissociation mechanism and stereochemical changes for trans - [M(LL)₂BX] with the help of suitable diagrams.

Ques 6.

Give suitable examples for trans-effect in octahedral complexes where CO and substituted phosphines are used as ligands.

Ques 7.

With the help of suitable diagrams explain the rearrangement of the cis  enantiomer by the bond rupture mechanism involving a trigonal bipyramidal intermediate.

Ques 8.

What are the salient features of an outer-sphere electron transfer mechanism?

Ques 9.

 Give the elementary steps and rate expression for the inner sphere mechanism which involves formation of a precursor complex.

Ques 10.

What are the ways by which the outer sphere electron transfer reaction is utilized to synthesize coordination compounds?

Ques 11.

What is there in the 5th position of deoxyhemoglobin? Explain with a suitable diagram. Give the relevant equations for the equilibrium constant regarding the oxygen binding by myoglobin.

Ques 12.

With suitable figures explain the arrangement of the subunits of the apoferretin shell.

Ques 13.

What is cytochrome c Oxidase? Also explain the role of cytochrome P450 in drug metabolism.

Ques 14.

Write a short note on rubredoxins.

Ques 15.

With suitable figures give the differences in the chemical structures of chlorophyll a and chlorophyll b,

Ques 16.

Explain "in vivo" and "in vitro" nitrogen fixation.

Ques 17.

With suitable diagrams explain which is the active Zn² site of carboxypeptidase A.

Ques 18.

Explain the transformation of xanthine to uric acid by xanthine oxidase

Ques 19.

What is the role of metal ion in protein-RNA interaction?

Ques 20.

Give a brief account on the toxic effects of metals.

Ques 21.

Give the classification of substitution mechanisms for octahedral complexes.

Ques 22.

Explain the mechanism of substitution reactions in trigonal bipyramidal complexes.

Ques 23.

With a suitable example suggest the order of the reactions of base-catalyzed hydrolyses and predict the mechanism that is followed in them.

Ques 24.

Explain with suitable figures the Bailar twist mechanism followed in intramolecular racemization reactions.

Ques 25.

Explain the dissociation mechanism and stereochemical changes for trans - [M(LL)₂BX] with the help of suitable diagrams.

Ques 26.

Give suitable examples for trans-effect in octahedral complexes where CO and substituted phosphines are used as ligands.

Ques 27.

With the help of suitable diagrams explain the rearrangement of the cis  enantiomer by the bond rupture mechanism involving a trigonal bipyramidal intermediate.

Ques 28.

What are the salient features of an outer-sphere electron transfer mechanism?

Ques 29.

 Give the elementary steps and rate expression for the inner sphere mechanism which involves formation of a precursor complex.

Ques 30.

What are the ways by which the outer sphere electron transfer reaction is utilized to synthesize coordination compounds?

Ques 31.

What is there in the 5th position of deoxyhemoglobin? Explain with a suitable diagram. Give the relevant equations for the equilibrium constant regarding the oxygen binding by myoglobin.

Ques 32.

With suitable figures explain the arrangement of the subunits of the apoferretin shell.

Ques 33.

What is cytochrome c Oxidase? Also explain the role of cytochrome P450 in drug metabolism.

Ques 34.

Write a short note on rubredoxins.

Ques 35.

With suitable figures give the differences in the chemical structures of chlorophyll a and chlorophyll b,

Ques 36.

Explain "in vivo" and "in vitro" nitrogen fixation.

Ques 37.

With suitable diagrams explain which is the active Zn² site of carboxypeptidase A.

Ques 38.

Explain the transformation of xanthine to uric acid by xanthine oxidase

Ques 39.

What is the role of metal ion in protein-RNA interaction?

Ques 40.

Give a brief account on the toxic effects of metals.

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