IGNOU MCH 13 SOLVED ASSIGNMENT

Ques 1.

Give the physical significance of Helmholtz energy.

Ques 2.

What is the effect of temperature on chemical potential?

Ques 3.

Explain the molecular partition function in brief.

Ques 4.

What is the improper rotation of the molecules? Explain with a suitable example.

Ques 5.

Give the characteristics of the unimolecular reactions.

Ques 6.

Define the primary and secondary salt effects on the rate of reactions in solution.

Ques 7.

Why the conventional kinetic methods are not useful to study the fast reactions?

Ques 8.

Determine the conditions for the spontaneity and equilibrium for following combinations of AH and AS for a given process.

(i)

(ii)

(iii)

(iv)

Ques 9.

Two moles of an ideal gas expand isothermally at 300 K from 7 bar to 3 bar. Calculate the change in the Helmholtz energy and Gibbs energy for the process.

Ques 10.

Define partial molar volume and give its physical significance.

Ques 11.

Give Stirling's approximation and outline its significance. Calculate the % error introduced in computing the value of 10! by using this approximation. (Given In 2=0.69 and In 3= 1.01)

Ques 12.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 13.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 14.

Derive an expression for the rotational partition function.

Ques 15.

Define Tetrahedral and Octahedral voids in three dimensional close packing.

Ques 16.

If atoms of element B form HCP lattice and 2/3rd of tetrahedral voids are occupied by those of the element A, what is the formula of the compound formed by the elements A and B?

Ques 17.

State the law of constancy of interfacial angles .

Ques 18.

Show the following planes in cubic unit cells

i) (110) in Primitive cubic cell

ii) (111) in Face-centred cubic cell and

iii) (200) in Body-centred cubic cell.

Ques 19.

Give the difference between screw Axis and glide Plane by using suitable illustrations.

Ques 20.

Identify all the symmetry elements in trans C₂H₂Cl₂or B₂Cl₆

Ques 21.

Give the salient features ofthe collision theory and calculate the factor that relates the collision theory with Arrhenius Equation.

Ques 22.

Discuss the Lindemann-Christiansen mechanism for unimolecular reactions and give the Hinshelwood's modification of this mechanism.

Ques 23.

What are two important features of the expression for rate of activation as per RRK theory?

Ques 24.

Give the principle of ultrasonic relaxation methods for the determination of the rates of the fast reactions.

Ques 25.

Explain the difference between homogeneous and heterogeneous catalysis with suitable examples.

Ques 26.

Describethe lock and key hypothesis of the enzyme action.

Ques 27.

What is the role of solvent in the Debye-Huckel model of a solution of an electrolyte?

Ques 28.

Why did we need the modification in the Debye-Huckel theory?

Ques 29.

Give the mathematical expressions of any two type of Maxwell and Boltzmann distribution of molecular speeds and name the terms involved.

Ques 30.

What is the effect of pressure and temperature on thermal conductivity?

Ques 31.

Derive the expression of the rate constant for reactions in solution in terms of activity where the reference standard state for the reactants is the gaseous state.

Ques 32.

What is the difference between diffusion controlled and activation-controlled reactions.

Ques 33.

Discuss the stopped flow method for the study of fast-reactions with suitable schematic diagram and outline its advantages over continuous flow method.

Ques 34.

What is adsorption in homogeneous catalysis? Derive an expression for Langmuir monolayer adsorption isotherms for adsorption at sufficiently low concentrations.

Ques 35.

What is the difference between competitive and uncompetitive enzyme inhibition?

Ques 36.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 37.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 38.

Write the basic assumptions of the Debye-Huckel theory.

Ques 39.

Calculate the ionic strength of

i) 0.08 mol kg¹ solutions of Ca(NO3)2 and

ii) the solution consisting of 6.3 g of MgCl2, 5 g of AlCl3 and 500 g of water.

Ques 40.

List different methods of experimental determination of activity coefficients.

Ques 41.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 42.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 43.

What are the limitations of phenomenological approach to transport properties?

Ques 44.

Using the Fick's first law of diffusion, derive the mathematical expression that provides the link between the phenomenological and thermodynamic treatment of diffusion phenomenon.

Ques 45.

Why is conductivity not a suitable quantity to compare the conduction behaviour of different electrolytic solutions?

Ques 46.

Define thermal conductivity. Why the thermal conductivity of gases is independent of pressure up to a reasonably high pressure.

Ques 47.

Give the physical significance of Helmholtz energy.

Ques 48.

What is the effect of temperature on chemical potential?

Ques 49.

Explain the molecular partition function in brief.

Ques 50.

What is the improper rotation of the molecules? Explain with a suitable example.

Ques 51.

Give the characteristics of the unimolecular reactions.

Ques 52.

Define the primary and secondary salt effects on the rate of reactions in solution.

Ques 53.

Why the conventional kinetic methods are not useful to study the fast reactions?

Ques 54.

Determine the conditions for the spontaneity and equilibrium for following combinations of AH and AS for a given process.

(i)

(ii)

(iii)

(iv)

Ques 55.

Two moles of an ideal gas expand isothermally at 300 K from 7 bar to 3 bar. Calculate the change in the Helmholtz energy and Gibbs energy for the process.

Ques 56.

Define partial molar volume and give its physical significance.

Ques 57.

Give Stirling's approximation and outline its significance. Calculate the % error introduced in computing the value of 10! by using this approximation. (Given In 2=0.69 and In 3= 1.01)

Ques 58.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 59.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 60.

Derive an expression for the rotational partition function.

Ques 61.

Define Tetrahedral and Octahedral voids in three dimensional close packing.

Ques 62.

If atoms of element B form HCP lattice and 2/3rd of tetrahedral voids are occupied by those of the element A, what is the formula of the compound formed by the elements A and B?

Ques 63.

State the law of constancy of interfacial angles .

Ques 64.

Show the following planes in cubic unit cells

i) (110) in Primitive cubic cell

ii) (111) in Face-centred cubic cell and

iii) (200) in Body-centred cubic cell.

Ques 65.

Give the difference between screw Axis and glide Plane by using suitable illustrations.

Ques 66.

Identify all the symmetry elements in trans C₂H₂Cl₂or B₂Cl₆

Ques 67.

Give the salient features ofthe collision theory and calculate the factor that relates the collision theory with Arrhenius Equation.

Ques 68.

Discuss the Lindemann-Christiansen mechanism for unimolecular reactions and give the Hinshelwood's modification of this mechanism.

Ques 69.

What are two important features of the expression for rate of activation as per RRK theory?

Ques 70.

Give the principle of ultrasonic relaxation methods for the determination of the rates of the fast reactions.

Ques 71.

Explain the difference between homogeneous and heterogeneous catalysis with suitable examples.

Ques 72.

Describethe lock and key hypothesis of the enzyme action.

Ques 73.

What is the role of solvent in the Debye-Huckel model of a solution of an electrolyte?

Ques 74.

Why did we need the modification in the Debye-Huckel theory?

Ques 75.

Give the mathematical expressions of any two type of Maxwell and Boltzmann distribution of molecular speeds and name the terms involved.

Ques 76.

What is the effect of pressure and temperature on thermal conductivity?

Ques 77.

Derive the expression of the rate constant for reactions in solution in terms of activity where the reference standard state for the reactants is the gaseous state.

Ques 78.

What is the difference between diffusion controlled and activation-controlled reactions.

Ques 79.

Discuss the stopped flow method for the study of fast-reactions with suitable schematic diagram and outline its advantages over continuous flow method.

Ques 80.

What is adsorption in homogeneous catalysis? Derive an expression for Langmuir monolayer adsorption isotherms for adsorption at sufficiently low concentrations.

Ques 81.

What is the difference between competitive and uncompetitive enzyme inhibition?

Ques 82.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 83.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 84.

Write the basic assumptions of the Debye-Huckel theory.

Ques 85.

Calculate the ionic strength of

i) 0.08 mol kg¹ solutions of Ca(NO3)2 and

ii) the solution consisting of 6.3 g of MgCl2, 5 g of AlCl3 and 500 g of water.

Ques 86.

List different methods of experimental determination of activity coefficients.

Ques 87.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 88.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 89.

What are the limitations of phenomenological approach to transport properties?

Ques 90.

Using the Fick's first law of diffusion, derive the mathematical expression that provides the link between the phenomenological and thermodynamic treatment of diffusion phenomenon.

Ques 91.

Why is conductivity not a suitable quantity to compare the conduction behaviour of different electrolytic solutions?

Ques 92.

Define thermal conductivity. Why the thermal conductivity of gases is independent of pressure up to a reasonably high pressure.

Ques 93.

Give the physical significance of Helmholtz energy.

Ques 94.

What is the effect of temperature on chemical potential?

Ques 95.

Explain the molecular partition function in brief.

Ques 96.

What is the improper rotation of the molecules? Explain with a suitable example.

Ques 97.

Give the characteristics of the unimolecular reactions.

Ques 98.

Define the primary and secondary salt effects on the rate of reactions in solution.

Ques 99.

Why the conventional kinetic methods are not useful to study the fast reactions?

Ques 100.

Determine the conditions for the spontaneity and equilibrium for following combinations of AH and AS for a given process.

(i)

(ii)

(iii)

(iv)

Ques 101.

Two moles of an ideal gas expand isothermally at 300 K from 7 bar to 3 bar. Calculate the change in the Helmholtz energy and Gibbs energy for the process.

Ques 102.

Define partial molar volume and give its physical significance.

Ques 103.

Give Stirling's approximation and outline its significance. Calculate the % error introduced in computing the value of 10! by using this approximation. (Given In 2=0.69 and In 3= 1.01)

Ques 104.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 105.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 106.

Derive an expression for the rotational partition function.

Ques 107.

Define Tetrahedral and Octahedral voids in three dimensional close packing.

Ques 108.

If atoms of element B form HCP lattice and 2/3rd of tetrahedral voids are occupied by those of the element A, what is the formula of the compound formed by the elements A and B?

Ques 109.

State the law of constancy of interfacial angles .

Ques 110.

Show the following planes in cubic unit cells

i) (110) in Primitive cubic cell

ii) (111) in Face-centred cubic cell and

iii) (200) in Body-centred cubic cell.

Ques 111.

Give the difference between screw Axis and glide Plane by using suitable illustrations.

Ques 112.

Identify all the symmetry elements in trans C₂H₂Cl₂or B₂Cl₆

Ques 113.

Give the salient features ofthe collision theory and calculate the factor that relates the collision theory with Arrhenius Equation.

Ques 114.

Discuss the Lindemann-Christiansen mechanism for unimolecular reactions and give the Hinshelwood's modification of this mechanism.

Ques 115.

What are two important features of the expression for rate of activation as per RRK theory?

Ques 116.

Give the principle of ultrasonic relaxation methods for the determination of the rates of the fast reactions.

Ques 117.

Explain the difference between homogeneous and heterogeneous catalysis with suitable examples.

Ques 118.

Describethe lock and key hypothesis of the enzyme action.

Ques 119.

What is the role of solvent in the Debye-Huckel model of a solution of an electrolyte?

Ques 120.

Why did we need the modification in the Debye-Huckel theory?

Ques 121.

Give the mathematical expressions of any two type of Maxwell and Boltzmann distribution of molecular speeds and name the terms involved.

Ques 122.

What is the effect of pressure and temperature on thermal conductivity?

Ques 123.

Derive the expression of the rate constant for reactions in solution in terms of activity where the reference standard state for the reactants is the gaseous state.

Ques 124.

What is the difference between diffusion controlled and activation-controlled reactions.

Ques 125.

Discuss the stopped flow method for the study of fast-reactions with suitable schematic diagram and outline its advantages over continuous flow method.

Ques 126.

What is adsorption in homogeneous catalysis? Derive an expression for Langmuir monolayer adsorption isotherms for adsorption at sufficiently low concentrations.

Ques 127.

What is the difference between competitive and uncompetitive enzyme inhibition?

Ques 128.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 129.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 130.

Write the basic assumptions of the Debye-Huckel theory.

Ques 131.

Calculate the ionic strength of

i) 0.08 mol kg¹ solutions of Ca(NO3)2 and

ii) the solution consisting of 6.3 g of MgCl2, 5 g of AlCl3 and 500 g of water.

Ques 132.

List different methods of experimental determination of activity coefficients.

Ques 133.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 134.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 135.

What are the limitations of phenomenological approach to transport properties?

Ques 136.

Using the Fick's first law of diffusion, derive the mathematical expression that provides the link between the phenomenological and thermodynamic treatment of diffusion phenomenon.

Ques 137.

Why is conductivity not a suitable quantity to compare the conduction behaviour of different electrolytic solutions?

Ques 138.

Define thermal conductivity. Why the thermal conductivity of gases is independent of pressure up to a reasonably high pressure.

Ques 139.

Give the physical significance of Helmholtz energy.

Ques 140.

What is the effect of temperature on chemical potential?

Ques 141.

Explain the molecular partition function in brief.

Ques 142.

What is the improper rotation of the molecules? Explain with a suitable example.

Ques 143.

Give the characteristics of the unimolecular reactions.

Ques 144.

Define the primary and secondary salt effects on the rate of reactions in solution.

Ques 145.

Why the conventional kinetic methods are not useful to study the fast reactions?

Ques 146.

Determine the conditions for the spontaneity and equilibrium for following combinations of AH and AS for a given process.

(i)

(ii)

(iii)

(iv)

Ques 147.

Two moles of an ideal gas expand isothermally at 300 K from 7 bar to 3 bar. Calculate the change in the Helmholtz energy and Gibbs energy for the process.

Ques 148.

Define partial molar volume and give its physical significance.

Ques 149.

Give Stirling's approximation and outline its significance. Calculate the % error introduced in computing the value of 10! by using this approximation. (Given In 2=0.69 and In 3= 1.01)

Ques 150.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 151.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 152.

Derive an expression for the rotational partition function.

Ques 153.

Define Tetrahedral and Octahedral voids in three dimensional close packing.

Ques 154.

If atoms of element B form HCP lattice and 2/3rd of tetrahedral voids are occupied by those of the element A, what is the formula of the compound formed by the elements A and B?

Ques 155.

State the law of constancy of interfacial angles .

Ques 156.

Show the following planes in cubic unit cells

i) (110) in Primitive cubic cell

ii) (111) in Face-centred cubic cell and

iii) (200) in Body-centred cubic cell.

Ques 157.

Give the difference between screw Axis and glide Plane by using suitable illustrations.

Ques 158.

Identify all the symmetry elements in trans C₂H₂Cl₂or B₂Cl₆

Ques 159.

Give the salient features ofthe collision theory and calculate the factor that relates the collision theory with Arrhenius Equation.

Ques 160.

Discuss the Lindemann-Christiansen mechanism for unimolecular reactions and give the Hinshelwood's modification of this mechanism.

Ques 161.

What are two important features of the expression for rate of activation as per RRK theory?

Ques 162.

Give the principle of ultrasonic relaxation methods for the determination of the rates of the fast reactions.

Ques 163.

Explain the difference between homogeneous and heterogeneous catalysis with suitable examples.

Ques 164.

Describethe lock and key hypothesis of the enzyme action.

Ques 165.

What is the role of solvent in the Debye-Huckel model of a solution of an electrolyte?

Ques 166.

Why did we need the modification in the Debye-Huckel theory?

Ques 167.

Give the mathematical expressions of any two type of Maxwell and Boltzmann distribution of molecular speeds and name the terms involved.

Ques 168.

What is the effect of pressure and temperature on thermal conductivity?

Ques 169.

Derive the expression of the rate constant for reactions in solution in terms of activity where the reference standard state for the reactants is the gaseous state.

Ques 170.

What is the difference between diffusion controlled and activation-controlled reactions.

Ques 171.

Discuss the stopped flow method for the study of fast-reactions with suitable schematic diagram and outline its advantages over continuous flow method.

Ques 172.

What is adsorption in homogeneous catalysis? Derive an expression for Langmuir monolayer adsorption isotherms for adsorption at sufficiently low concentrations.

Ques 173.

What is the difference between competitive and uncompetitive enzyme inhibition?

Ques 174.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 175.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 176.

Write the basic assumptions of the Debye-Huckel theory.

Ques 177.

Calculate the ionic strength of

i) 0.08 mol kg¹ solutions of Ca(NO3)2 and

ii) the solution consisting of 6.3 g of MgCl2, 5 g of AlCl3 and 500 g of water.

Ques 178.

List different methods of experimental determination of activity coefficients.

Ques 179.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 180.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 181.

What are the limitations of phenomenological approach to transport properties?

Ques 182.

Using the Fick's first law of diffusion, derive the mathematical expression that provides the link between the phenomenological and thermodynamic treatment of diffusion phenomenon.

Ques 183.

Why is conductivity not a suitable quantity to compare the conduction behaviour of different electrolytic solutions?

Ques 184.

Define thermal conductivity. Why the thermal conductivity of gases is independent of pressure up to a reasonably high pressure.

Ques 185.

Give the physical significance of Helmholtz energy.

Ques 186.

What is the effect of temperature on chemical potential?

Ques 187.

Explain the molecular partition function in brief.

Ques 188.

What is the improper rotation of the molecules? Explain with a suitable example.

Ques 189.

Give the characteristics of the unimolecular reactions.

Ques 190.

Define the primary and secondary salt effects on the rate of reactions in solution.

Ques 191.

Why the conventional kinetic methods are not useful to study the fast reactions?

Ques 192.

Determine the conditions for the spontaneity and equilibrium for following combinations of AH and AS for a given process.

(i)

(ii)

(iii)

(iv)

Ques 193.

Two moles of an ideal gas expand isothermally at 300 K from 7 bar to 3 bar. Calculate the change in the Helmholtz energy and Gibbs energy for the process.

Ques 194.

Define partial molar volume and give its physical significance.

Ques 195.

Give Stirling's approximation and outline its significance. Calculate the % error introduced in computing the value of 10! by using this approximation. (Given In 2=0.69 and In 3= 1.01)

Ques 196.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 197.

A system consist of two energy level 60 and 61 which are singly and triple degenerate, respectively. Calculate the partition function of the system.

Ques 198.

Derive an expression for the rotational partition function.

Ques 199.

Define Tetrahedral and Octahedral voids in three dimensional close packing.

Ques 200.

If atoms of element B form HCP lattice and 2/3rd of tetrahedral voids are occupied by those of the element A, what is the formula of the compound formed by the elements A and B?

Ques 201.

State the law of constancy of interfacial angles .

Ques 202.

Show the following planes in cubic unit cells

i) (110) in Primitive cubic cell

ii) (111) in Face-centred cubic cell and

iii) (200) in Body-centred cubic cell.

Ques 203.

Give the difference between screw Axis and glide Plane by using suitable illustrations.

Ques 204.

Identify all the symmetry elements in trans C₂H₂Cl₂or B₂Cl₆

Ques 205.

Give the salient features ofthe collision theory and calculate the factor that relates the collision theory with Arrhenius Equation.

Ques 206.

Discuss the Lindemann-Christiansen mechanism for unimolecular reactions and give the Hinshelwood's modification of this mechanism.

Ques 207.

What are two important features of the expression for rate of activation as per RRK theory?

Ques 208.

Give the principle of ultrasonic relaxation methods for the determination of the rates of the fast reactions.

Ques 209.

Explain the difference between homogeneous and heterogeneous catalysis with suitable examples.

Ques 210.

Describethe lock and key hypothesis of the enzyme action.

Ques 211.

What is the role of solvent in the Debye-Huckel model of a solution of an electrolyte?

Ques 212.

Why did we need the modification in the Debye-Huckel theory?

Ques 213.

Give the mathematical expressions of any two type of Maxwell and Boltzmann distribution of molecular speeds and name the terms involved.

Ques 214.

What is the effect of pressure and temperature on thermal conductivity?

Ques 215.

Derive the expression of the rate constant for reactions in solution in terms of activity where the reference standard state for the reactants is the gaseous state.

Ques 216.

What is the difference between diffusion controlled and activation-controlled reactions.

Ques 217.

Discuss the stopped flow method for the study of fast-reactions with suitable schematic diagram and outline its advantages over continuous flow method.

Ques 218.

What is adsorption in homogeneous catalysis? Derive an expression for Langmuir monolayer adsorption isotherms for adsorption at sufficiently low concentrations.

Ques 219.

What is the difference between competitive and uncompetitive enzyme inhibition?

Ques 220.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 221.

Derive the mathematical rate expression for competitive enzyme inhibition and give the graphical representation of Lineweaver-Burk plot.

Ques 222.

Write the basic assumptions of the Debye-Huckel theory.

Ques 223.

Calculate the ionic strength of

i) 0.08 mol kg¹ solutions of Ca(NO3)2 and

ii) the solution consisting of 6.3 g of MgCl2, 5 g of AlCl3 and 500 g of water.

Ques 224.

List different methods of experimental determination of activity coefficients.

Ques 225.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 226.

Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

Ques 227.

What are the limitations of phenomenological approach to transport properties?

Ques 228.

Using the Fick's first law of diffusion, derive the mathematical expression that provides the link between the phenomenological and thermodynamic treatment of diffusion phenomenon.

Ques 229.

Why is conductivity not a suitable quantity to compare the conduction behaviour of different electrolytic solutions?

Ques 230.

Define thermal conductivity. Why the thermal conductivity of gases is independent of pressure up to a reasonably high pressure.

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